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Heat is a killer of all batteries and high temperatures cannot always be avoided.This is the case with a battery inside a laptop,a starter battery under the hood of a car and stationary batteries in a tin shelter under the hot sun.As a guideline,each 8°C (15°F) rise in temperature cuts the life of a sealed lead acid battery in half.A VRLA batteryfor stationary applications that would last 10 years at 25°C (77°F) would only live for five years if operated at 33°C (95°F).Once the battery is damaged by heat,the capacity cannot be restored.The life of a battery also depends on the activity and is shortened if the battery is stressed with frequent discharge.

According to the 2010 BCI Failure Mode Study,starter batteries have become more heat-resistant over the past 10 years.In the 2000 study,a change of 7°C (12°F) affected battery life by roughly one year; in 2010 the heat tolerance has widened to 12°C (22°F).In 1962,a starter battery lasted 34 months,and in 2000 the life expectancy had increased to 41 months.In 2010,BCI reports an average age of 55 months of use.The cooler North attains 59 months and the warmer South 47 months.

Cranking the engine poses minimal stress on a starter battery.This changes in a start-stop function of a micro hybrid.The micro hybrid turns the IC engine off at a red traffic light and restarts it when the traffic flows.This results in about 2,000 micro cycles per year.Data obtained from car manufacturers show a capacity drop to about 60 percent after two years of use in this configuration.To solve the problem,automakers are using specialty AGM and other variations that are more robust than the regular lead acid.Figure 5 shows the drop in capacity after 700 micro cycles.The simulated start-stop test was performed in Cadex laboratories.

Water permeation,or loss of electrolyte,is a concern with sealed lead acid batteries,and overcharging contributes to this condition.While flooded systems accept water,a fill-up is not possible with VRLA.Adding water has been tried,but this does not offer a reliable fix.Experimenting with watering turns the VRLA into unreliable battery that needs high maintenance.Flooded lead acid batteries are one of the most reliable systems.

With good maintenance these batteries last up to 20 years.The disadvantages are the need for watering and providing good ventilation.When VRLA was introduced in the 1980s,manufacturers claimed similar life expectancy to flooded systems,and the telecom industry switched to these maintenance-free batteries.By mid 1990 it became apparent that the life for VRLA did not replicate that of a flooded type;the useful service life was limited to only 5�C10 years.It was furthermore noticed that exposing the batteries to temperatures above 40°C (104°F) could cause a thermal runaway condition due to dry-out.

A new lead acid battery should have an open circuit voltage of 2.125V/cell.At this time,the battery is fully charged.During buyer acceptance,the lead acid may drop to between 2.120V and 2.125V/cell.Shipping,dealer storage and installation will decrease the voltage further but the battery should never go much below 2.10V/cell.This would cause sulfation.Battery type,applying a charge or discharge within 24 hours before taking a voltage measurement,as well as temperature will affect the voltage reading.A lower temperature lowers the OCV;warm ambient raises it.

Test method: The test battery was fully charged and then discharged to 70 percent to resemble the SoC of a micro hybrid in real life.The battery was then discharged at 25A for 40 seconds to simulate engine off condition at stoplight with the headlight on,before cranking the engine at 400A and recharging.The CCA readings were taken with the Spectro CA-12.The cell voltages on a battery string must be similar,and this is especially important for higher-voltage VRLA batteries.

With time,individual cells fall out of line,and applying an equalizing charge every six months or so should theoretically bring the cells back to similar voltage levels.While equalizing will boost the needy cells,the healthy cell get stressed if the equalizing charge is applied carelessly.What makes this service so difficult is the inability to accurately measure the condition of each cell and provide the right dose of remedy.Gel and AGM batteries have lower overcharge acceptance than the flooded version and different equalizing conditions apply.Always refer to the manufacturer's specifications.

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Let's examine the aging mechanism of batteries in terms of fading capacity and increasing internal resistance.Figure 1 shows a battery with high capacity and another that has aged.The battery capacity loss is illustrated with growing «rock content;»the rocks mark the unusable part of the battery.Figure 2 looks at resistance and illustrates a good battery with a free-flowing tap and a high-resistance one with restricted flow.

Automotive technicians are most familiar with CCA,but this reading reflects engine cranking only.Capacity,the energy storage component,remains mostly unknown.Figure 3 illustrates the relationship between CCA and capacity on hand of a fluid-filled container.The liquid represents capacity and the taps symbolize CCA at different loading capabilities.

Batteries 1 to 9 perform well on capacity and CCA,but batteries 10 to 20 show notable capacity loss while the CCA remains strong.The motorist is unaware of the fading capacity until the car won't start one morning.This is especially critical during a cold spell,which further reduces the capacity.Capacity is the leading health indicator of a battery,and car manufacturers often use 65 percent as the pass/fail threshold for warranty replacement.This magic level forms a natural bend,a cliff between a high performing battery and one that is beginning to age.

Most rechargeable batteries maintain low internal resistance during the service life,and this reflects in a high CCA (cold cranking amps) on starter batteries.Capacity,on the other hand,begins to drop gradually as the battery ages.To study these changes,Cadex measured the capacity and CCA of 20 aging starter batteries.The results are laid out in Figure 4,sorted according to capacity levels in percentage.

Service garages usually take 40 percent as an end-of-life indication.Even though a starter battery with 40 percent capacity may still crank well and have 6 to 12 months of service left before it will finally quit,the battery should be replaced.Thrifty drivers,(including this author) prefer to wait,but invariably get caught with a dead battery at the worst possible moment.Evaluating the capacity of a starter battery gives the most accurate end-of-life prediction.Capacity sets the floor upon which CCA and other readings are compared.Without knowing capacity,other measurements mean little.

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All batteries are affected by self-discharge.The battery self-discharge is not a manufacturing defect but a battery characteristic,although poor manufacturing practices and improper handling can increase the problem.The amount of electrical self-discharge varies with battery type and chemistry.Primary cells such as lithium battery and alkaline retain the stored energy best and can be kept in storage for several years.Figure 1 illustrates self-discharge in the form of leaking fluid.

Among rechargeable batteries,lead acid has the lowest self-discharge and loses only about five percent per month.With age and usage,however,the flooded lead acid builds up sludge in the sediment trap,which causes a soft short when this semi-conductive substance reaches the plates.Nickel-based rechargeable batteries leak the most and need recharging before use when placing them on the shelf for a few weeks.High-performance ni-mh battery and nickel-based batteries have a higher self-discharge than the standard versions.

Furthermore,self-discharge increases with use and age,and the contributing factors are crystalline formation (memory),permitting the battery to «cook» in the charger or exposing it to repeated harsh deep discharge cycles.Lithium-ion self-discharges about five percent in the first 24 hours and then loses 1 to 2 percent per month;the protection circuit adds another three percent per month.A faulty separator can lead to a high self-discharge and if critical,the electrical current will generate enough heat that can in extreme cases lead to a thermal breakdown.Table 2 shows the typical self-discharge of battery systems.

The energy loss is asymptotical,meaning that the self-discharge is highest right after charge and then tapers off.Nickel-based batteries lose 10 to 15 percent of their capacity in the first 24 hours after charge,then 10 to 15 percent per month.Figure 3 shows the typical loss of a nickel-based battery while in storage.

The self-discharge on all battery chemistries increases at higher temperature and the rate typically doubles with every 10°C (18°F).A noticeable energy loss occurs if a battery is left in a hot vehicle.High cycle count and aging also increase self-discharge.Nickel-metal-hydride is good for 300-400 cycles,whereas the standard nickel-cadmium lasts for over 1,000 cycles before elevated self-discharge starts interfering with performance.The self-discharge on an older nickel-based battery can get so high that the pack loses its energy through leakage rather than normal use.

Under normal circumstances the self-discharge of Li-ion 18650 battery is reasonably steady throughout its service life;however a full state-of-charge and elevated temperature increase the self-discharge.These very same factors also affect longevity,a phenomenon that applies to most batteries.Table 4 shows the self-discharge per month of Li-ion at various temperatures and state-of-charge.The high self-discharge at full state-of-charge may come as a surprise to many.This explains in part the asymptotical self-discharge characteristic when removing a battery from the charger.

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